Organic Chemistry

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Author: Leroy G. Wade

ISBN-10: 032159231X

ISBN-13: 9780321592316

Category: Organic Chemistry

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Organized around functional groups, this book incorporates problem-solving help, orientation features, and complete discussions of mechanisms. Wade explains concepts without taking the unnecessary short cuts that often lead to misconceptions—his hallmark problem-solving approach includes unique strategies and hints to help readers focus on the individual steps of each reaction and how they contribute to the overall reaction. Wade also employs the most efficient method of mechanism boxes with its two-tiered approach: Mechanism and Key Mechanism Boxes. He delineates the 20 “Key” mechanisms that comprise nearly all of the mechanisms students will encounter. Therefore, the book takes one additional and important step in helping readers identify and grapple with the smallest number of the most important concepts to understand. Acid-Base Chemistry, Lewis Structures, Bronsted, Electron Structure (shell, orbitals, magnetic shielding), Bonding (formation, patterns, polarity, MO), Resonance, Stereochemistry, MO Theory, Conformational analysis, Thermodynamics, Kinetics, Reaction Coordinate diagrams, Chirality, Regioselectivity, Synthesis, Aromaticity, Carbonyl chemistry. A comprehensive reference for chemistry professionals. Booknews New edition of a text first published in 1987. The text has been microedited, with many large passages rewritten to enhance clarity. Annotation c. Book News, Inc., Portland, OR (booknews.com)

Preface1Introduction and Review12Structure and Properties of Organic Molecules403Structure and Stereochemistry of Alkanes834The Study of Chemical Reactions1315Stereochemistry1746Alkyl Halides: Nucleophilic Substitution and Elimination2267Structure and Synthesis of Alkenes2948Reactions of Alkenes3309Alkynes38310Structure and Synthesis of Alcohols41611Reactions of Alcohols45712Infrared Spectroscopy and Mass Spectrometry50013Nuclear Magnetic Resonance Spectroscopy54414Ethers, Epoxides, and Sulfides61015Conjugated Systems, Orbital Symmetry, and Ultraviolet Spectroscopy64716Aromatic Compounds69017Reactions of Aromatic Compounds73218Ketones and Aldehydes78519Amines84620Carboxylic Acids90921Carboxylic Acid Derivatives94722Alpha Substitutions and Condensations of Enols and Enolate Ions100823Carbohydrates and Nucleic Acids106024Amino Acids, Peptides, and Proteins111825Lipids116426Synthetic Polymers1184Appendices1205Answers to Selected ProblemsIndex